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Redox Reactions
1. Redox reactions involve a TRANSFER of ELECTRONS from substance A to substance B.
When electrons are transferred, charge numbers of ions change.
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As an example, assume an Fe2+ ion changes to the Fe3+ ion.
When numbers have changed, such a reaction is called a REDOX reaction.
(There are many reactions where these numbers do not change.)
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2. Assume A loses electrons :
A is said to have undergone an oxidation ½ reaction (O½R)
(the charge numbers increase)
A itself is called a reducing agent (RA) (since A would have caused such a reaction in B)
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3. Substance B would gain these electrons
B is said to have undergone a reduction ½ reaction (R½R)
(the charge numbers decrease)
B itself is called an oxidising agent (since B would have caused such a reaction in A)
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Easy ways to remember
The triple statement. The “three words” go together.
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O½R
loss of e-
RA
We say the Fe2+ ion has undergone an oxidation ½ reaction, by losing electrons. The Fe2+ ion is called a reducing agent.
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R½R
gain of e-
OA
We say the Mn+7 ion has undergone a reduction ½ reaction, by gaining electrons. The Mn+7 ion is called an oxidising agent.
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N.B. All you have to do is to check whether the charge numbers increase or decrease for a particular substance on either side of the arrow.
If the charge increases, then it is an O½R
If the charge decreases, then it is a R½R