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Redox Reactions

1.       Redox reactions involve a TRANSFER of ELECTRONS from substance A to substance B.

          When electrons are transferred, charge numbers of ions change.

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          As an example, assume an Fe2+ ion changes to the Fe3+ ion.

          When numbers have changed, such a reaction is called a REDOX reaction.

          (There are many reactions where these numbers do not change.)

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2.       Assume A loses electrons :

A is said to have undergone an oxidation ½ reaction (O½R)

(the charge numbers increase)

A itself is called a reducing agent (RA) (since A would have caused such a reaction in B)

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3.       Substance B would gain these electrons

          B is said to have undergone a reduction ½ reaction  (R½R)

          (the charge numbers decrease)

          B itself is called an oxidising agent (since B would have caused such a reaction in A)

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Easy ways to remember

The triple statement. The “three words” go together.

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O½R       

loss of e-        

RA

 

 

 

 

 

 

 

 

 

 

We say the Fe2+ ion has undergone an oxidation ½ reaction, by losing electrons. The Fe2+ ion is called a reducing agent.

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R½R       

gain of e- 

OA      

 

 

 

 

 

 

 

 

We say the Mn+7 ion has undergone a reduction ½ reaction, by gaining electrons. The Mn+7   ion is called an oxidising agent.

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N.B. All you have to do is to check whether the charge numbers increase or decrease for a particular substance on either side of the arrow.

If the charge increases, then it is an O½R

If the charge decreases, then it is a R½R

 

Science Copyright©  V. Gokal

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